Experimental Investigation of metals and Antioxidants on Oxidation Stability and Cold flow properties of Pongamia Biodiesel and its blends

Gaurav Dwivedi, Puneet Verma, mahendra pal sharma

Abstract


Due to fluctuation in fuel prices in recent times the Indian economy is facing a heavy burden on the economic front to meet the energy supply demand. Due to large gap between the supply and demand of petroleum products. The government of India and various other organizations are working on the development of alternative fuel to petro diesel. Pongamia oil (PO) is being identified as second most important source of biodiesel production in India after Jatropha. But the poor stability and cold flow property associated with the Pongamia biodiesel make it difficult for using it as alternative fuel to diesel. The storage of biodiesel is the major issue for its long term utilization. The aim of current work is to investigate the storage impact of various metals on oxidation stability and cold flow property of Pongamia biofuel. The experimental results shows that oxidation stability of various metal varies in order of Iron>Aluminium> Zinc while all these material deteriorate the cloud and pour point of Pongamia biodiesel and make it unsuitable for its long term use. But the use of antioxidant Pyrogallol improves the oxidation stability of Pongamia biodiesel but it has no significant effect on its cold flow properties. The finding also reveals that Pongamia biodiesel can be stored in metal container only when there is addition of antioxidant to meet the standard of biodiesel.


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Keywords


Pongamia; Biodiesel; Fuel; Oxidation stability; Cloud Point; Pour Point; Cold filter plugging point; Iron; Aluminum; Zinc

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References


G. Dwivedi, M.P. Sharma, Application of Box–Behnken design in optimization of biodiesel yield from Pongamia oil and its stability analysis, Fuel. 145 (2015) 256–262

M. Canakci, A. Monyem, J. Van Gerpen, Accelerated Oxidation Processes In Biodiesel, Transactions of the ASAE. 42(6)(1999)1565-1572,

Serrano M., Oliveros R., Sánchez M., Moraschini A., Martínez M., Aracil J., Influence of blending vegetable oil methyl esters on biodiesel fuel properties: Oxidative stability and cold flow properties. Energy. 65, 109-115 (2014).

G. Dwivedi, M.P. Sharma,Investigation and Improvement in CFP of Pongamia biodiesel, Waste and Biomass Valorization. 6(1) (2015) 73-79

P. Kumar, G. Dwivedi, M.P. Sharma,Assessment of oxidation stability of oil for biodiesel production, Vivechan International Journal of Research. 5(1)(2014) 8-12

D.S. Rawat, G. Joshi, B.Y. Lamba, A.K.Tiwari, S. Mallick, Impact of additives on storage stability of Karanja (PongamiaPinnata) biodiesel blends with conventional diesel sold at retail outlets, Fuel. 120 (2014) 30–37

G. Dwivedi, M.P. Sharma, Prospects of biodiesel from Pongamia in India, Renew. Sustain. Energy Rev. 32 (2014) 114–122

Christensen E., McCormick R.L., Long-term storage stability of biodiesel and biodiesel blends. Fuel Processing Technology. 128, 339–348 (2014).

G. Dwivedi, M.P.Sharma “Investigation of Cold Flow Properties of Waste Cooking Biodiesel” Journal of Clean Energy Technologies, Vol 3(4), pp. 205-208, 2016

Biodiesel Handling and Use Guide Fourth Edition, NREL/TP-540-43672 Revised January 2009

E. Natarajan, Stability Studies of Biodiesel, International Journal of Energy Science. 2(4) (2012) 152-155

https://www.michigan.gov/.../mdot/MDOT_Research__Report_RC-1545...

S. Jain, M.P. Sharma, Oxidation and thermal behavior of Jatrophacurcas biodiesel influenced by antioxidants and metal contaminants, International Journal of Engineering Science and Technology. 3(4) (2011) 65-75

G. Dwivedi, M.P. Sharma, Impact of Antioxidant and Metals on Biodiesel Stability-A Review, J. Mater. Environ. Sci. 5 (5) (2014) 1412-1425

S. Jain, M.P. Sharma, Effect of metal contents on oxidation stability of biodiesel/diesel blends, Fuel 116 (2014) 14–18

A. Sarin, R. Arora, N.P. Singh, M. Sharma, R. K. Malhotra, Influence of metal contaminants on oxidation stability of Jatropha biodiesel, Energy 34 (2009) 1271–1275

P. Verma , M.P. Sharma, G. Dwivedi, Investigation of Metals and Antioxidants on Stability Characteristics of Biodiesel, Materials Today: Proceedings 2 (2015) 3196-3202


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